The program IRPal is a powerful tool for the interpretation of IR-spectra of organic compounds. It not only gives the user one or more functional groups that feature absorption band(s) for a selected wave number, but relates that information to the possible existence of other bands in the spectrum that could confirm these assignments. Thus, if we assign a peak at 1700 cm-1 to a carbonyl stretch of an aromatic aldehyde the program prompts the user to check the presence of aldehyde C-H at 2720 and 2820 cm-1 and a number of typical aromatic C-H out of plane bands. Apart from this, one can rule out classes of compounds by making them invisible to the user. If a sample is known not to contain nitrogen, one can hide all amine, amide, nitrile, etc.
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